New polynuclear carbonyl complexes containing iron with cobalt or rhodium
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 654-658
- https://doi.org/10.1039/j19700000654
Abstract
The reaction of Fe2(CO)9 with (π-C5H5)M(CO)2](M = Co or Rh) has led to the preparation of five new polynuclear carbonyl complexes containing iron with cobalt or rhodium. The structure of these new ‘mixed-metal’ complexes has been inferred from a combination of i.r., n.m.r., and Mössbauer spectroscopic data and is discussed in relation to the structures of known polynuclear carbonyls such as Fe3(CO)12 and (π-C5H5)3Rh3(CO)3.Keywords
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