Co-ordinating tendencies of the hexafluorophosphate ion
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2279-2281
- https://doi.org/10.1039/j19710002279
Abstract
The compounds Cu(py)4(PF6)2, Ni(py)6(PF6)2, Ni(py)4(PF6)2, and Ni(4-mepy)4(PF6)2(py = pyridine and 4-mepy = 4-methylpyridine) have been prepared and characterized. The magnetic moment, electronic and i.r. spectral data are interpreted as indicating that the PF6 – ion has less co-ordinating ability than the ClO4 – and BF4 – ions.Keywords
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