Two dielectric contributions due to domain/cluster structure in the ferroelectrics with diffused phase transitions

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Abstract
The main dielectric contributions and the structure of dielectric spectrum of the ferroelectrics with diffused phase transitions are considered on the base of PbMg1/3Nb2/3O3 (PMN) crystals investigation. Dielectric spectra of the displacive, order-disorder and diffused phase transitions ferroelectrics are compared. Dielectric properties of the PMN are nontypical for displacive-type ferroelectrics and aren't defined mainly by soft phonon mode. The main polarization mechanisms are caused by the thermoactivated dynamics of the metastable polar phase clusters and polar - nonpolar phase boundaries.

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