Studies on Enantioselective Addition of Chiral Titanium Reagents to Aromatic Aldehydes
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (04) , 291-292
- https://doi.org/10.1055/s-1989-27227
Abstract
A series of substituted chiral benzhydrols were synthesized by reaction of aromatic aldehydes with the chiral intermediates formed from chiral titanates and arylmagnesium halides. The effect of substituents on the enantioselectivity of the reaction is studied. The reactions are carried out with two different chiral intermediates using two different procedures.Keywords
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