Kinetics and mechanisms of redox reactions in aqueous solutions. Part I. The reaction between cyanoferrate(III) and iodide
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 679-683
- https://doi.org/10.1039/j19680000679
Abstract
Kinetics of the initial-stages of the reaction 2Fe(CN)6 3–+ 21–= 2Fe(CN)6 4–+ l2 have been measured. The reaction normally observed is a cation-catalysed process, although specific ion effects caused by both cations and anions may be present. The rate of reaction is relatively insensitive to general ionic-strength effects. The suggested mechanism is in agreement with the observed kinetic form, and we are able to include the interpretation of previously published data.Keywords
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