Triazoles. Part IX. 1,2,4-Triazolyl ketones
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 824-830
- https://doi.org/10.1039/j39680000824
Abstract
3-Benzoyl-1,2,4-triazole and 1- and 5-substituted 1,2,4-triazol-3-yl aryl ketones have been prepared by the oxidation of the corresponding 3-benzyl-1,2,4-triazoles. The Beckmann rearrangement of the oximes of 1-phenyl-3-benzoyl-1,2,4-triazole was studied. Unusual i.r. bands of 3-aroyl-5-pyridyl-1,2,4-triazoles are ascribed to proton tunnellng.Keywords
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