The thermal rearrangement of a 4-thia-1-azabicyclo[4,1,0]hept-2-ene

Abstract
(6S)-3-Methoxycarbonyl-5,5-dimethyl-4-thia-1-azabicyclo[4,1,0]hept-2-ene is converted into 2,3-dihydro-(3R)-(2-propenyl)-6-methoxycarbonyl-1,4-thiazine in boiling toluene.

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