Fused Salt Polarography Using a Dropping Bismuth Cathode
- 1 January 1960
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 107 (10) , 824-828
- https://doi.org/10.1149/1.2427522
Abstract
An apparatus is described which is suitable to study fused chlorides by the polarographic technique. Dropping bismuth is used in a way analogous to dropping mercury. Polarographic waves are shown for , , and in a eutectic melt at 450°C. The method serves as an analytical tool at high temperatures, besides yielding physicochemical information such as diffusion coefficients by application of the Ilkovic equation.Keywords
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