Synthesis, Characterization, and Reactivity of Cationic Hydride [HPd(diphosphine)2]+CF3SO3-, the Missing Member of the Family [HM(dppe)2]+X- (M = Ni, Pd, Pt). DFT QM/MM Structural Predictions for the [HPd(dppe)2]+ Moiety
- 19 November 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 41 (25) , 6550-6552
- https://doi.org/10.1021/ic020631p
Abstract
The synthesis, characterization, and properties of the cationic hydride [HPd(dppe)(2)](+)CF(3)SO3(-).1/8THF, the missing member of the family [HM(dppe)(2)](+)X(-) (M = Ni, Pd, Pt), are described. The Pd hydride is not stable in solution and may react as either a proton or a hydride donor. DFT QM/MM calculations of the [HPd(dppe)(2)](+) moiety have allowed us to predict its structure and reactivity.Keywords
This publication has 5 references indexed in Scilit:
- Comprehensive Thermodynamic Characterization of the Metal−Hydrogen Bond in a Series of Cobalt-Hydride ComplexesJournal of the American Chemical Society, 2002
- Measurement of the Hydride Donor Abilities of [HM(diphosphine)2]+ Complexes (M = Ni, Pt) by Heterolytic Activation of HydrogenJournal of the American Chemical Society, 2002
- Tetraphenylborate coordination chemistry. Synthesis, solid-state and solution characterization, and properties of {[(C2H4)2Rh(.eta.6-Ph)]2BPh2}O3SCF3 and {[(C2H4)2Rh(.eta.6-Ph)]3BPh}(O3SCF3)2: the first examples of a tetraphenylborate anion acting as a 12- or 18-e donor to metal centersOrganometallics, 1993
- Oxidative cleavage of tetramethylammonium pentacarbonyl(1-oxyalkylidene)chromate(0) complexes: formation of carboxylic acid derivativesOrganometallics, 1992
- Azido complexes of nickel(II), palladium(II), and platinum(II)Inorganic Chemistry, 1970