The stereochemistry of oxidation of 1-amino-cyclopropanecarboxylic acid
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 206-207
- https://doi.org/10.1039/c39850000206
Abstract
Whereas hypochlorite oxidation of 1-amino-cis-[2,3-2H2]cyclopropane carboxylic acid yields ethylene with retention of stereochemistry the use of transition metal oxidants, such as copper(II), permanganate, and ferrate ions gives completely scrambled cis- and trans-[1,2-2H2]ethylene as is found in the biosynthetic process.Keywords
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