Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol
- 26 February 2009
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 2035-2037
- https://doi.org/10.1039/b822942b
Abstract
Direct conversion of tetrahydrofurfuryl alcohol, which is one of the biomass-derived chemicals, to 1,5-pentanediol was realized by chemoselective hydrogenolysis catalyzed by Rh/SiO2 modified with ReOx species, and this reaction route gave higher yield than the conventional multi-step method.Keywords
This publication has 17 references indexed in Scilit:
- Chemical Routes for the Transformation of Biomass into ChemicalsChemical Reviews, 2007
- Catalytic performance of Rh/SiO2 in glycerol reaction under hydrogenGreen Chemistry, 2007
- Selective deoxygenation of sugar polyols to α,ω-diols and other oxygen content reduced materials—a new challenge to homogeneous ionic hydrogenation and hydrogenolysis catalysisDalton Transactions, 2006
- Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and EngineeringChemical Reviews, 2006
- Glycerol conversion in the aqueous solution under hydrogen over Ru/C + an ion-exchange resin and its reaction mechanismJournal of Catalysis, 2006
- Effect of sulfur and temperature on ruthenium-catalyzed glycerol hydrogenolysis to glycolsJournal of Catalysis, 2005
- Low-pressure hydrogenolysis of glycerol to propylene glycolApplied Catalysis A: General, 2005
- Unsaturated O- and N-Heterocycles from Carbohydrate FeedstocksAccounts of Chemical Research, 2002
- Preparation of Dihydropyran, δ-Hydroxyvaleraldehyde and 1,5-Pentanediol from Tetrahydrofurfuryl AlcoholJournal of the American Chemical Society, 1946
- THE CATALYTIC HYDROGENATION OF ORGANIC COMPOUNDS OVER COPPER CHROMITEJournal of the American Chemical Society, 1931