Chiral base-mediated benzylic functionalisation of (alkyl benzyl ether)tricarbonylchromium(0) complexes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 839-840
- https://doi.org/10.1039/cc9960000839
Abstract
Asymmetric functionalisation of the benzylic methylene group in tricarbonylchromium(0) complexes of alkyl benzyl ethers[(PhCH2OR)(CO)3Cr0] is achived in high yield (86–96%) and high enantiomeric excess (ee)(97 to 99%) using chiral base methodology.Keywords
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