Hydrogen–deuterium exchange between LiBH₄and LiBD₄. Isotope effects on the¹H and¹¹B nuclear magnetic resonance spectra of species LiBH_nD_{4 –n}

1 January 1974

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 8,p. 294-295
https://doi.org/10.1039/c39740000294

Abstract

Isotope effects on the ¹¹B–H coupling constant and on the ¹H and ¹¹B chemical shifts are observed in the n.m.r. spectra of the mixture of species, LiBH_nD_{4 –n}(n= 0–4), produced by H–D exchange between LiBH₄ and LiBD₄.

Keywords

ISOTOPE EFFECT
NUCLEAR MAGNETIC RESONANCE

Hydrogen–deuterium exchange between LiBH4and LiBD4. Isotope effects on the1H and11B nuclear magnetic resonance spectra of species LiBHnD4 –n

Abstract

Keywords

Hydrogen–deuterium exchange between LiBH₄and LiBD₄. Isotope effects on the¹H and¹¹B nuclear magnetic resonance spectra of species LiBH_nD_{4 –n}