Synthesis of Silicon-Functionalized Dimethylsilyl Enol Ethers from Ketones
- 1 June 1991
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 21 (12-13) , 1337-1351
- https://doi.org/10.1080/00397919108021281
Abstract
Symmetrical dimethylsilyl bis-enol ethers are obtained in good yield by reaction of ketones with dichlorodimethylsilane in the presence of triethylamine and sodium iodide. Reaction of ketones with N, N - diethylaminodimethylchlorosilane in the presence of triethylamine and sodium iodide followed by subsequent conversions provides a useful synthesis of silicon-functionalized dimethylsilyl enol ethers including unsymmetrical dimethylsilyl bis-enol ethersKeywords
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