Crystal Structures and Electrical Resistivities of Three-Component Organic Conductors: (BEDT-TTF)2MM′(SCN)4 [M = K, Rb, Cs; M′ = Co, Zn, Cd]
- 1 April 1995
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 68 (4) , 1136-1144
- https://doi.org/10.1246/bcsj.68.1136
Abstract
New three-component organic conductors, (BEDT-TTF)2MM′(SCN)4 [M = K, Rb, Cs; M′ = Co, Zn, Cd], are prepared. The crystal structure analyses of α-ET2CsCo(SCN)4, ETZn(SCN)3, α-ET2RbZn(SCN)4, α-ET2CsZn(SCN)4, α-ETCd0.66(SCN)2, and ET2CsCd(SCN)4 are carried out. Most of salts have the α-type donor arrangement and the polymer sheet like [···M′2+···(SCN)−···M+···] in a thick anion layer. Especially α-(BEDT-TTF)2CsM′(SCN)4 [M′ = Co and Zn] are metallic down to 20 K.This publication has 11 references indexed in Scilit:
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