A New Radical Vinylation Reaction of Iodides and Dithiocarbonates
- 12 July 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (13-14) , 1943-1946
- https://doi.org/10.1002/(sici)1521-3773(19990712)38:13/14<1943::aid-anie1943>3.0.co;2-r
Abstract
Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq. (1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.Keywords
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