Photolysis of Aqueous Solutions of Hydrogen Peroxide Containing β-Ammonio Alcohols
Open Access
- 1 November 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (21) , 3589-3598
- https://doi.org/10.1139/v74-537
Abstract
During the photolysis of aqueous H2O2 added β-ammonio alcohols suffer oxidative attack initiated through hydrogen abstraction by the •OH radical. At pH 7.0 the initially formed radical,[Formula: see text] undergoes fragmentation to yield [Formula: see text] and CH3COR′ exclusively. At pH 1.0 fragmentation is less important and direct oxidation to [Formula: see text] dominates. A radical deprotonation step is proposed to account for the pH dependence.Keywords
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