Diasteoselective conjugate additions reactions of a lithiated allylic sulfoximine to acyclic enones

Abstract
The conjugate addition reactions of lithiated N-p-tosyl S-phenyl-2-enyl sulfoximine 4 with cyclic and acyclic enones gives exclusively 1,4-α adducts, the reactions with acyclic enones are highly diastereoselective.

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