The unimolecular decomposition of excited biradicals formed by the addition of triplet 14C-methylene to cis- or trans-but-2-ene
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 193-194
- https://doi.org/10.1039/c39720000193
Abstract
Unimolecular decomposition by CH3 loss has been observed with a half-pressure for stabilization of about 75 Torr for the excited biradicals formed by the addition of triplet 3(14CH2) to both cis-and trans-but-2-ene; as much as 9% of the 14C activity is found in C8 compounds formed by radical combination reactions of 14C-labelled butenyl radicals.Keywords
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