Time-dependent photodissociation of methyl iodide with five active modes

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Abstract
Advances in the time propagation of multidimensional wave packets are exploited to present the A‐band photodissociation dynamics of methyl iodide for five active vibrational modes on the three relevant excited ab initio potential surfaces. The five modes considered represent all of the experimentally observed dynamical activity. The only modes neglected are the asymmetric C–H stretch and the asymmetric deformation of the methyl group. The kinetic energy operator corresponding to these five degrees of freedom is derived. The fully quantum mechanical calculation was implemented upon grids using 2880 distinct time‐dependent configurations, determined by the multiconfigurational time‐dependent Hartree algorithm, for each electronic state. All of the currently known experimental results regarding the umbrella vibration, symmetric C–H stretching vibration, perpendicular rotation, and parallel rotation of the photodissociated methyl radical fragment are well reproduced. The full wavelength dependence of all of these quantities is determined. The wavelength dependence of the energy deposited into translational, vibrational, and rotational motion is also given. The time evolution of the modes is presented in the context of correlated motion and its effect upon the dissociative process. Many of the details of the dynamics inherent to the conically intersecting nature of the excited surfaces is delineated. In particular it is shown that the Jahn–Teller distortion of the 1Q1 state is irrelevant in contributing to the perpendicular character of resonance Raman depolarization ratios. Results are compared and contrasted to previous calculations employing the collinear pseudotriatomic model with optimized empirical surfaces or the bent pseudotriatomic model with the same ab initio surfaces.