Synthesis and reactivity of bimetallic Au–Ag complexes. X-Ray structure of a chain polymer containing the moiety…(F5C6)2Au(µ-AgSC4H8)2Au(C6F5)2…
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1097-1098
- https://doi.org/10.1039/c39810001097
Abstract
The 1 : 1 reaction between [Bu4N][Au(C6F5)2] and AgCIO4 in dichloromethane gives yellow solutions, from which solids of stoicheiometry Au(C6F5)AgL can be precipitated by the addition of O, N, S, or P-donors, L; and X-ray diffraction study for L = SC4H8 reveals [AuAg]2 rings linked by Au ⋯ Au interactions to form infinite metal-atom chains.Keywords
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