Neutron diffraction study on formation and structure of DxTaS2 and HxNbS2
- 1 June 1979
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 70 (11) , 5203-5212
- https://doi.org/10.1063/1.437363
Abstract
Cathodic reduction of 2H–TaS2 in D2SO4 was investigated by transient neutron powder diffractometry. Deuterium was found to enter the lattice in a regular way. The structural model proposed implies a strong Ta–D bond. Single crystal neutron diffraction data on H0.76NbS2 confirm the position of hydrogen in a three‐center metal bond inside the dichalcogenide layers. Structural data are in accordance with inelastic neutron scattering data.Keywords
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