Organo-Aluminium Compounds. I. Preparation and Properties of Some Phenylaluminium Compounds
- 1 January 1963
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 16 (5) , 794-800
- https://doi.org/10.1071/ch9630794
Abstract
Reaction of phenylmagnesium halides with aluminium chloride affords a good route to triphenylaluminium etherate and hence to triphenylaluminium, diphenylaluminium chloride, and phenylaluminium dichloride. The molecular weights of these compounds were determined ebulliometrically. Diphenylaluminium chloride and phenylaluminium dichloride form mono-etherates. Possible reactions with benzene, toluene, chloroform, mercuric chloride, and organic halides were examined. A convenient preparation of diphenylmercury is described.Keywords
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