Effect of a High cis-Barrier on the Microwave Spectrum of Hydrogen Peroxide
- 1 May 1955
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (5) , 942-946
- https://doi.org/10.1063/1.1742152
Abstract
The frequency spectrum in the microwave region and the Stark effect are obtained for the case of a potential function with a high cis‐peak and a low trans‐peak. Using the presently available experimental data on H2O2 it is not possible to determine whether this potential function or the cis‐peak equal trans‐peak potential function is correct. It is shown, however, that the microwave data can answer this question if sufficient resolution is obtained.Keywords
This publication has 4 references indexed in Scilit:
- The Microwave Spectrum of Hydrogen PeroxideThe Journal of Chemical Physics, 1954
- The Stark Effect for a Rigid Asymmetric RotorThe Journal of Chemical Physics, 1948
- The Asymmetric Rotor II. Calculation of Dipole Intensities and Line ClassificationThe Journal of Chemical Physics, 1944
- Hindered Rotation in Methyl AlcoholPhysical Review B, 1940