Reduction to Standard Heat of Combustion of Bomb Calorimetric Data for Organic Bromine Compounds.

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Abstract
The rigorous Washburn reduction of combustion calorimetric data for organic bromine compounds is discussed and applied to a recent high-precision moving-bomb method. The general scheme for the reduction is treated in two respects: (i) The accuracy of the reduction is improved by presentation of experimental data for the auxiliary numerical quantities entering some of the more important corrections. For As2O3-As2O3-HBr solutions of various composition, data are thus given for, (a) the density at 20 and 25[degree]C, (b) the heat capacity at 25[degree]C, and (c) the solubility of carbon dioxide at 20 and 25[degree]C. (ii) The general scheme is modified to apply specificially to the above-mentioned bomb calorimetric method.

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