Adsorption and Degradation of the Weak Acid Mesotrione in Soil and Environmental Fate Implications

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Abstract
The ability of soils to adsorb and degrade pesticides strongly influences their environmental fate. This paper examines the adsorption and degradation of a weak acid, a new herbicide mesotrione [2‐[4‐(methylsulfonyl)‐2‐nitrobenzoyl]‐1,3‐cyclohexanedione], in 15 different soils from Europe and the USA. Experiments were conducted to understand the influence of soil properties, covering a wide range of soil textures, soil pH values (4.4 to 7.5), and organic carbon contents (0.6 to 3.35%). Mesotrione adsorption (Kdvalues ranged from 0.13 to 5.0 L/kg) was primarily related to soil pH, and to a lesser extent by percent organic carbon (%OC). As soil pH rose, mesotrioneKdvalues got smaller as mesotrione dissociated from the molecular to anionic form. Mesotrione degradation (half‐lives ranged from 4.5 to 32 d) was also related to soil pH, getting shorter as soil pH rose. Simple regression of mesotrione adsorption against soil pH and %OC and against degradation provided a close fit to the data. The correlation between mesotrione adsorption and degradation means thatKdand half‐life values are only relevant for use in environmental fate assessment if these values are “paired” for the same soil pH and %OC. The implications were as illustrated for leaching, raising important issues about combining pesticide adsorption and degradation behavior in environmental fate assessments.