Mechanism of ligand substitution in weak complexes. Part 4
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 2101-2107
- https://doi.org/10.1039/tf9716702101
Abstract
For Al[Co(CN)6] the thermodynamics and kinetics of the reaction outer-sphere complex inner-sphere complex have been investigated. From measurements with the pressure-jump relaxation technique between 10 and 40°C the rates and energies of activation have been obtained. The equilibrium constants were determined by the conductometric method and from the amplitude of the relaxation effect.Keywords
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