K-Absorption Spectral Investigations on Some Cobalt Complexes Involving Sulphur-Ligands

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Abstract
K-absorption edges of Cobalt in some complexes involving sulphur-ligands have been examined. The ligand-field splitting of 3d-orbitals is found to show up in the low energy region of the K-edge. These complexes have large 10 Dq values as estimated from electronic spectra. Edge-widths and edge-shifts have been measured and their correlation respectively to coordination stoichiometry and valency of the metal ion has been discussed. Splitting of the K-absorption maximum has been observed.

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