Synthesis and characterization of novel molybdenum(III) confacial bioctahedral complexes: X-ray crystal structures of [Ph4P][(Me2S)-Cl2Mo(µ-Cl)3MoCl2(SMe2)] and (Me2S)Cl2Mo(µ-Me2S)(µ-Cl)2MoCl2-(SMe2)
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 899-901
- https://doi.org/10.1039/c39820000899
Abstract
The reaction of Et3SiH with MoCl4(Me2S)2 produces a series of isomeric molybdenum(III) complexes with the general formula Mo2Cl6(Me2S)3; X-Ray crystallographic results and/or1H n.m.r. and analytical data establish the existence of the antiferromagnetic species, (Me2S)Cl2Mo(µ-Cl)3MoCl(SMe2)2(1)[meso-and (+), (–)-forms], its chloro-anionic derivative, [Ph4P][(Me2S)Cl2Mo(µ-Cl)3MoCl2](2), and the diamagnetic complex, (Me2S)Cl2Mo(µ-Me2S)(µ-Cl)2MoCl2)(SMe2)(3).Keywords
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