RESOLUTION OF ENANTIOMERS BY HPLC ON CELLULOSE TRANS- AND CIS-TRIS(4-PHENYLAZOPHENYLCARBAMATE)
- 5 June 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (6) , 983-986
- https://doi.org/10.1246/cl.1986.983
Abstract
Cellulose tris(4-phenylazophenylcarbamate) (CPAPC) having azobenzene pendant groups was adsorbed on silica gel to use as a chiral stationary phase for HPLC. Pure trans-CPAPC resolved many racemic compounds, whereas 70% cis-CPAPC showed very poor resolving power.Keywords
This publication has 6 references indexed in Scilit:
- Photo-controlled adsorption chromatography.Polymers, 1986
- Chromatographic resolution: IX. High-performance liquid chromatographic resolution of enantiomers on optically active poly(triphenylmethyl methacrylate)Journal of Chromatography A, 1985
- Chromatographic resolution. 7. Useful chiral packing materials for high-performance liquid chromatographic resolution of enantiomers: phenylcarbamates of polysaccharides coated on silica gelJournal of the American Chemical Society, 1984
- Polymers having the capability of resolving enantiomers.Journal of Synthetic Organic Chemistry, Japan, 1984
- Photoresponsive polymers. 5. Reversible solubility change of polystyrene having azobenzene pendant groupsMacromolecules, 1983
- Chromatographic Resolution of Racemates. New analytical methods (17)Angewandte Chemie International Edition in English, 1980