Novel two-coordinate germanium(II) arylamides: Ge(NHAr)2, ArN[Ge(NHAr)]2(µ-NAr) and [Ge(µ-NAr)]22, and the X-ray structures of 2 and Sn(NHAr)2(Ar = C6H2But3-2,4,6)
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1587-1589
- https://doi.org/10.1039/c39900001587
Abstract
Depending on reaction conditions, treatment of GeCl2(1,4-dioxane) with [Li(µ-NHAr)(L)]2(L = OEt2 or OC4H8) yields Ge(NHAr)21 or the first binuclear group 14 element(II) amides [Ge(µ-NAr)]22 or ArN[Ge(NHAr)]2(µ-NAr)3; X-ray structural data are presented on the tin analogue of 1 and on the germetane 2.Keywords
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