Preparation, first X-ray structure analysis and reactivity of hexacoordinate silicon compounds with a tetradentate azomethine ligand
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1289-1290
- https://doi.org/10.1039/a803060j
Abstract
Hexacoordinate silicon compounds and polymers with the tetradentate azomethine ligand N,N′-ethylenebis(2-hydroxyacetophenoneiminate) (H2salen*) have been prepared and characterized; the X-ray structure analysis of (salen*)SiF2 clearly demonstrates the octahedral coordination of the silicon atom.Keywords
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