Asymmetric aldol reaction of 2-cyanopropionates catalysed by trans-chelating chiral diphosphine ligand TRAP–rhodium(I) complex
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 71-72
- https://doi.org/10.1039/a706662g
Abstract
trans-Chelating chiral diphosphine TRAP ligands bearing P-aromatic groups are effective for RhI-catalysed asymmetric aldol reaction of 2-cyanopropionates with an aldehyde to give the corresponding aldol adduct with up to 93% ee.Keywords
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