Kinetic salt effects on reactions of the solvated electron in methanol
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 63, 1191-1197
- https://doi.org/10.1039/tf9676301191
Abstract
The effect of ionic strength on the rate constant ratios k(e– s+Ag+)/k(e– s+N2O) and k(e– s+H+)/k(e– s+N2O) has been studied in the γ-radiolysis of methanol. The different magnitudes of this effect in systems containing Ag+ and H+ ions emphasize the importance of ion size in the Brϕnsted-Bjerrum treatment of ionic reactions in this solvent. The data presented are consistent with the solvated electron in methanol having unit negative charge and an effective diameter of 5 Å.Keywords
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