Deuterium NMR as a structural probe for micelle-associated carbohydrates: D-mannose.
- 1 December 1983
- journal article
- research article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 80 (23) , 7192-7196
- https://doi.org/10.1073/pnas.80.23.7192
Abstract
Residual quadrupole splittings for deuterons on perdeuterated .alpha.- and .beta.-D-mannose oriented in a potassium laurate liquid crystal were measured. Multiple quantum 2-dimensional NMR spectroscopy at a high magnetic field is used to gain sufficient resolution to assign splittings to specific sites within these molecules. The assigned splittings are interpreted in terms of molecular geometries and preferred orientations of the molecules relative to the surface of the potassium laurate micelles that make up the liquid crystalline phase.This publication has 8 references indexed in Scilit:
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