Halogeno-complexes of cobalt(I) and nickel(I) with 1,1,1-tris(diphenylphosphinomethyl)ethane
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1213-1216
- https://doi.org/10.1039/dt9720001213
Abstract
The terdentate ligand 1,1,1-tris(diphenylphosphinomethyl)ethane (I) forms cobalt- and nickel-(I) complexes of general formula MLX (X = Cl, Br, or I). Spectral and magnetic data on the compounds are presented. They are non-electrolytes, are all isomorphous (X-rays) with the analogous Cu1 complexes, and probably have a pseudotetrahedral structure.Keywords
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