HIGHLY ENANTIOSELECTIVE ALDOL REACTION OF METHYL KETONES VIA CHIRAL STANNOUS AZAENOLATES
- 5 August 1984
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (8) , 1399-1402
- https://doi.org/10.1246/cl.1984.1399
Abstract
Chiral 1,3-oxazolidines are readily prepared from methyl ketones and chiral norephedrine. Formation of stannous azaenolates from the oxazolidines and reaction with aldehydes followed by removal of the chiral auxiliary lead to the aldol products in high level of enantiomeric purity.This publication has 8 references indexed in Scilit:
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