New Dinuclear Iridium(II) Complexes Arising by Oxidative Addition of I2 to [Ir2(μ‐StBu)2 (CO)2L2]
- 1 July 1980
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 19 (7) , 551-552
- https://doi.org/10.1002/anie.198005511
Abstract
The small family of iridium (II) complexes has increased in size. In the case of (1), L = CO and L = PMe3, the reaction shown below leads to two isomers each, which do not interconvert. The product having L = PMe2Ph has been characterized by X‐ray structure analysis. equation imageKeywords
This publication has 7 references indexed in Scilit:
- Dinuclear bridged d8 metal complexes : IX. Preparation and structure of the complexes [Ir2(μ-SBu-t)2(CO)2(PR3)2] and [Ir2(μ-SBu-t)2(CO)3(PR3)]Journal of Organometallic Chemistry, 1980
- Thiolato-bridged dinuclear d8 iridium(I) complexes and their hydrogenation to form dihydridodiiridium(II)(Ir-Ir) complexes. Crystal and molecular structures of [Ir(.mu.-SBu-t)(CO)(P(OMe)3)]2 and of [Ir(H)(.mu.-SBu-t)(CO)(P(OMe)3)]2Journal of the American Chemical Society, 1979
- Electrochemistry of coordination compounds XV. Paramagnetic hydrido complexes of cobalt(II), rhodium(II) and iridium(II)Journal of Organometallic Chemistry, 1977
- Preparation and x-ray crystal and molecular structure of μ-sulfurdioxidebis(hydridodicarbonyltriphenylphosphineiridium)Journal of Organometallic Chemistry, 1974
- Mechanistic studies of oxidative addition to low-valent metal complexes. II. Reactions of .alpha.-bromo estersJournal of the American Chemical Society, 1973
- Tricyclohexylphosphine complexes of rhodium(I), rhodium(II), iridium(I) and iridium(III)Journal of Inorganic and Nuclear Chemistry, 1973
- Oxidative addition to iridium(I). Free-radical processJournal of the American Chemical Society, 1972