Sporidesmins. Part 16. The structure of chetomin, a toxic metabolite of Chaetomium cochliodes, by nitrogen-15 and carbon-13 nuclear magnetic resonance spectroscopy
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 1248-1251
- https://doi.org/10.1039/p19780001248
Abstract
Analysis of the 13C and 15N n.m.r. spectra of [15N6] chetomin biosynthesized by Chaetomium cochliodes established that the sporidesmin-like and 3-(ω-skatyl)-3,6-epidithiopiperazine-2,5-dione fragments are linked by a bond between the indole nitrogen and the quaternary β-indoline carbon.This publication has 4 references indexed in Scilit:
- Sporidesmins. XV, The 13C nuclear magnetic resonance spectra of sporidesmin and sporidesmin-D. The evidence in the spectra for strain imposed by an epidithio bridgeAustralian Journal of Chemistry, 1976
- THE BIOLOGICAL PROPERTIES OF 3,6-EPIDITHIADIKETOPIPERAZINES: INHIBITION OF GROWTH OF BACILLUS SUBTILIS BY GLIOTOXINS, SPORIDESMINS, AND CHETOMINCanadian Journal of Microbiology, 1966
- Chaetomin, a New Antibiotic Substance Produced by Chaetomium cochliodesJournal of Bacteriology, 1944
- Chaetomin, a New Antibiotic Substance Produced by Chaetomium cochliodesJournal of Bacteriology, 1944