Conversion of racemic 2-hydroxymethyl[5]thiaheterohelicene into a single enantiomer on the uptake by bovine serum albumin
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1521-1522
- https://doi.org/10.1039/c39940001521
Abstract
Racemic 2-hydroxymethylthieno[3,2-e:4,5-e′]di[1]benzothiophene with a labile helical structure was converted into a (P) enantiomer upon uptake by bovine serum albumin, in which the existence of two substrate-binding sites with a distinct ability to recognize chirality was revealed.Keywords
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