Preparation of, and problems in the assignment of configuration of, some optically active alkyl-transition metal compounds
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 571-572
- https://doi.org/10.1039/c29710000571
Abstract
Optically active (1-methylheptyl)bis(dimethyl-glyoximinato)pyridine-cobalt(III) and -rhodium(III) have been prepared from (–)-1-methylheptyl bromide; cleave age of the organocobalt compound with bromine regenerates (–)-1-methylheptyl bromide of greater than 50% optical purity.Keywords
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