Synthesis and spectroscopy of tert-butylimido complexes of osmium(VI) and ruthenium(VI) porphyrins

1 January 1992

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 2,p. 161-163
https://doi.org/10.1039/c39920000161

Abstract

Oxidative deprotonation of [M(P)(NH₂Bu^t)2][M = Ru, Os; P= porphyrin dianion] gives [Ru(P)(O)(NBu^t)], [Os(P)(O)(NBu^t)]and [OS(P)(NBu^t)₂], which are characterised by IR and ¹H NMR spectroscopy.

Keywords

TERT
BUTYLIMIDO
NH2BUT
RUTHENIUM
NMR
DEPROTONATION
OSMIUM
CHARACTERISED
DIANION

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