The redox nature of the reaction of β-rhenium(IV) chloride with triphenylphosphine in acetonitrile, and the crystal structure of the reduction product trichloro(acetonitrile)bis(triphenylphosphine)rhenium(III)
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 10,p. 600-601
- https://doi.org/10.1039/c29700000600
Abstract
An unusual redox reaction of β-rhenium(IV) chloride with triphenylphosphine in acetonitrile is described, and the crystal structure of one of the reduction products, ReCl3,2PPh3,MeCN shows that this molecule contains σ-bonded acetonitrile.Keywords
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