The tetracarbonyl trianions of manganese and rhenium, M(CO)4 3?
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 966-967
- https://doi.org/10.1039/c39750000966
Abstract
Alkali metal reduction of M2(CO)10 or M(CO)5 –(M Mn and Re) in hexamethylphosphoramide provides the first non-cluster binary metal carbonyl trianions, M(CO)4 3–, which are characterized by their spectral and chemical properties.Keywords
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