Effect of translational temperature anisotropy on the rotational distribution of N2 in the Ar free jet
- 1 August 1982
- journal article
- Published by AIP Publishing in Physics of Fluids
- Vol. 25 (8) , 1346-1348
- https://doi.org/10.1063/1.863914
Abstract
The effect of the translational temperature anisotropy T∥≳T⊥ on the rotational distribution yj, temperature Tr, and collision number Zr of N2 in the Ar free jet is studied at the lower density level P0d = 15 Torr-mm using the ellipsoidal velocity distribution and the rotational transition cross section of the power law. The effect of T∥≳T⊥ is appreciable. The overpopulation of the higher rotational levels j above the Boltzmann distribution fitted to the distribution of the lower j, i.e., the degree of nonequilibrium for the case T∥≳T⊥ = Ti (i≡isentropic) is slightly less pronounced than for the case T∥ = T⊥ = Ti but more pronounced than for the case T∥ = T⊥≳Ti. The ratio yj/y0, Tr, and the terminal Zr for T∥≳T⊥ = Ti are larger than for T∥ = T⊥ = Ti but smaller than for T∥ = T⊥≳Ti.Keywords
This publication has 7 references indexed in Scilit:
- Rotational distribution of N2 in Ar free jetPhysics of Fluids, 1981
- State resolved rotational relaxation of CO in the free jet expansion of He–CO mixturesThe Journal of Chemical Physics, 1981
- Power law scaling for rotational energy transferThe Journal of Chemical Physics, 1979
- Surprisal analysis of classical trajectory calculations of rotationally inelastic cross sections for the Ar–N2 system; influence of the potential energy surfaceThe Journal of Chemical Physics, 1976
- Translational nonequilibrium in free jet expansionsPhysics of Fluids, 1974
- Relaxation rates from time of flight analysis of molecular beamsThe Journal of Chemical Physics, 1974
- Electron Beam Studies of the Diffusive Separation of Helium-Argon MixturesPhysics of Fluids, 1966