Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2379-2380
- https://doi.org/10.1039/a906560a
Abstract
Dichlorophenylborane reacts smoothly with [Li- (tmen)][CH2PPh2] in THF to afford, in good yields, the Li(tmen)+ salt of a novel monoanionic tridentate phosphinoborate, tris(diphenylphosphinomethyl)phenylborate; reaction of the ligand with SnCl2 produces tris(diphenylphosphinomethyl) phenylboratotin(II) chloride, which may be dehalogenated to give the η3 compound, {[PhB- (CH2PPh2)3]Sn}PF6, tris(diphenylphosphinomethyl)- phenylboratotin(II) hexafluorophosphate.Keywords
This publication has 0 references indexed in Scilit: