Crystal structures of two organo-manganese complexes formed by acetyl migration to a co-ordinated double bond

Abstract
The structures of a delocalised pseudo-π-allylic (three electron)π-oxopropyl manganese tricarbonyl complex (A) and a σ-bonded Mn–C oxobutyl tricarbonyl complex (B) have been determined by three-dimensional X-ray structural analysis.

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