Antiferromagnetic Interaction Achieved by a 3-D Supramolecular CuII Complex with Pyrazino-Fused TTF as the Ligand, [CuCl2(BP-TTF)]
- 18 August 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (19) , 7575-7577
- https://doi.org/10.1021/ic060746j
Abstract
The diffusion reaction of TBA2CuIICl4 (TBA = tetrabutylammonium) and a N-containing organic donor, BP-TTF [=bis(pyrazino)tetrathiafulvalene], yielded a 3-D supramolecular Cu complex, [CuCl2(BP-TTF)] (1). The magnetic measurement of 1 exhibits an antiferromagnetic interaction by fitting a Bonner−Fisher model from 2 to 300 K with S = 1/2 and J = −3.5 K between CuΙΙ mediated by self-assembling donor columns.Keywords
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