Rotational-level mixing and intracollisional interference in the pure rotational spectrum of HD gas

1 February 1985

journal article
research article
Published by American Physical Society (APS) in Physical Review A

Vol. 31 (2) , 1160-1163
https://doi.org/10.1103/physreva.31.1160

Abstract

Rotational-level mixing by anisotropic intermolecular forces is found to be important to the mechanism which produces intracollisional interference effects in the pure rotational spectrum of HD and HD–inert-gas mixtures. The major contribution involves the anisotropic repulsive term in the potential and the anisotropic overlap-induced dipole moment. Improved agreement between calculation and experiment results when the mixing is included in the analysis.

Keywords

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