Thallium(I) derivatives of β-diketones, phenols and carboxylic acids
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2007-2012
- https://doi.org/10.1039/j19710002007
Abstract
A number of thallium(I) derivatives of β-diketones, phenols, and carboxylic acids have been prepared. The u.v. spectra in a variety of aprotic and protic solvents have been observed and interpreted. The results suggest that the thallium–oxygen bond in these derivatives has considerably more covalent character than the analogous alkali-metal–oxygen bonds. The mass spectra have been recorded, and dimeric species observed. Attempts to prepare complexes of these derivatives are reported.Keywords
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